1830. He dissolved the gum in spirits of turpentine and invented

steam-heated rolls for spreading it upon cloth. Companies were formed to exploit the products, and in the fall and winter of 1833 and 1834 many thousands of dollars’ worth of goods were made by the Roxbury Company, but the business proved a total failure, for in the summer the goods melted, decomposed and became so offensive as to be worse than useless, while the cold of winter rendered them stiff and liable to crack. With a knowledge of these facts and conditions Charles Goodyear commenced his experiments, believing that there was a great future for this material if it could only be prevented from melting in summer and stiffening in winter. He tried mixing it with many materials, first using magnesia, which, however, proved ineffective. On June 17, 1837, he took out patent No. 240, in which he proposed to destroy the adhesive properties of caoutchouc by superficial application of an acid solution of the metals, nitric acid with copper or bismuth being specially recommended. He also claimed the incorporation of lime with the gum to bleach it. Under this process Mr. Goodyear made various articles in the form of fabrics, toys and ornamental articles, using the fabric to make clothing for himself, which he wore to demonstrate its value and wearing qualities. A striking word picture of Mr. Goodyear at this time is given by the reply of a gentleman who, being asked by a man looking for Mr. Goodyear as to how he might recognize him, replied, “If you meet a man who has on an India rubber cap, stock, coat, vest, and shoes, and an India rubber money purse in his pocket, without a cent of money in it, that is he.” Many useful and artistic articles were made under this first patented process, including maps, surgical bandages, etc., and were brought by Mr. Goodyear to the notice of President Jackson, Henry Clay and John C. Calhoun, from whom he received very encouraging letters. His efforts, however, to introduce his process commercially were not attended with success. Capitalists and manufacturers had been rendered so conservative by the large loss of money in the Roxbury Company, that they were disinclined to have anything further to do with it. Practically alone he was obliged to continue his work. By the kindness of Mr. Chaffee and Mr. Haskins he was allowed the use of the valuable machinery standing idle in their factory at Roxbury, and he made shoes, piano covers, table cloths and carriage covers of superior quality, and from the sale of these, and of licenses to manufacture, he for the first time was able to support his family in comfort. Mr. Goodyear had not yet discovered, however, the process of vulcanization, upon which the rubber industry is founded. In 1838 Mr. Nathaniel Hayward, of Woburn, Mass., who had been employed in the bankrupt rubber company, discovered that the stickiness of the rubber could be prevented by spreading a small quantity of sulphur on it. The same result had also been noticed by a German chemist. On Feb. 24, 1839, Mr. Hayward procured the patent, No. 1,090, on his process, and assigned it to Mr. Goodyear. The patent covered a process of dissolving sulphur in oil of turpentine and mixing it with the gum, and also included the incorporation of the dry flowers of sulphur with the gum, the product afterwards being treated by Mr. Goodyear’s metallic salt process. This was the starting point of vulcanization, for vulcanization consists simply in admixing sulphur with the rubber, and then subjecting it for six to eight hours to a temperature of about 300°. Its effect is to so change the nature of the gum to prevent it from melting or becoming sticky under the influence of heat, or of hardening and becoming stiff under the influence of cold, the vulcanized gum remaining elastic, impervious, and unchangeable under all ordinary conditions. This great discovery of the influence of heat on the sulphur treated gum was quite accidental and wholly unexpected. Heat above all things was the agency which in all previous observations was most to be feared, for it was this more than anything else that melted down, decomposed and destroyed all of his manufactured articles. While sitting near a hot stove engaged in an animated discussion concerning his experiments, a piece of the gum treated with sulphur, which he held in his hand, was, by a rapid gesture, thrown upon the stove. To his astonishment, he found that this relatively high heat did not melt it, as heretofore, and while it charred slightly, it was not made at all sticky. He nailed the piece of gum outside the kitchen door in the intense cold, and upon examining it the next morning found it as perfectly flexible as when he put it out. Goodyear had discovered the process which afterwards came to be known as “vulcanization.” The discovery was made in 1839, but was not accepted by those to whom it was submitted as possessing any importance. Prof. Silliman, of Yale College, however, in the fall of 1839 testified to the results claimed for it by Mr. Goodyear--that it did not melt with heat, nor stiffen with the cold. On June 15, 1844, Mr. Goodyear took out his celebrated patent, No. 3,633, covering this process, in which he not only used sulphur, but added a proportion of white lead. The proportions named were 25 parts of rubber, 5 parts of sulphur, and 7 parts of white lead, the ingredients either to be ground in spirits of turpentine, or to be incorporated dry between rolls. The odor imparted by the sulphur was to be destroyed by washing with potash or vinegar. This patent was reissued in two divisions Dec. 25, 1849, and again on Nov. 20, 1860, and was extended for seven years from June 15, 1858, which was the end of the first term. Under this patent two kinds of rubber were made and sold--“soft rubber,” containing only a small proportion of sulphur, while the other, known as the “vulcanite,” “ebonite,” or “hard rubber,” had from 25 to 35 per cent. of sulphur and was subjected to a longer heat. The history of this patent is a remarkable one. Immensely valuable as it was, Goodyear reaped but a small share of the profit, for in the midst of his poverty and necessities he was obliged to sell licenses and establish royalties at a figure far below the real value of the rights conveyed. Some idea of the great value of the business which Mr. Goodyear had developed may be had from the fact that the companies who held rights under the patent for the manufacture of shoes paid at one time to Daniel Webster the enormous fee of $25,000 for defending their patent interests. With the idea of extending his invention Mr. Goodyear visited England in 1851, where he found that Thomas Hancock, of the house of Macintosh & Co., had forestalled him, although not the inventor. A peculiar provision of the English patent law, which gives the patent to the first introducer, permitted this. Nothing daunted, however, he organized a magnificent exhibit for the Great International Exhibition held in Crystal Palace at Hyde Park, London, in 1851. This exhibit cost him $30,000, and he called it the Goodyear Vulcanite Court. It comprehended an elegantly constructed suite of open rooms made of hard rubber ornamented with handsome carvings, and furnished with rubber furniture, musical instruments, and globes made of rubber, and it was also carpeted with the same material. For his exhibit he received the “Grand Council Medal,” which was one of the highest testimonials of the exposition. This exhibit was afterwards moved from London to Sydenham, where it was exposed and used as an agency for some years for the sale of rubber goods. [Illustration: FIG. 161.--MACHINE FOR GRINDING AND WASHING CRUDE RUBBER.] Mr. Goodyear had obtained a French patent for his invention, and at the Exposition Universelle in Paris, in 1855, he fitted up at an expense of $50,000 two elegant courts with India rubber furniture, caskets and rich jewelry, and for this exhibit he had conferred upon him by the Emperor Napoleon the “Grand Medal of Honor” and the “Cross of the Legion of Honor.” It was a singular instance of the irony of fate that the decoration of the “Cross of the Legion of Honor” should have been conveyed to him while imprisoned for debt in “Clichy,” the debtors’ prison in Paris. The lofty courage of the man was well illustrated at this time in his reply to his wife’s solicitous inquiries as to how he had spent the night while in prison. He said, “I have been through nearly every form of trial that human flesh is heir to, and I find that _there is nothing in life to fear but sin_.” The declining years of his life were full of sorrow, pain and affliction, and at his death in 1860 his estate was $200,000 in debt. He lived long enough, however, to see his material applied to nearly five hundred uses, giving employment in England, France and Germany to 60,000 persons, and producing in this country alone goods worth $8,000,000 a year. [Illustration: FIG. 162.--MAKING RUBBER CLOTH.] The greatest of all applications of rubber are to be found in the manufacture of boots and shoes. The number of attacks of cold, rheumatism, and death-dealing diseases from wet feet, that have been averted by the use of rubber shoes, can never be estimated, but perhaps it is safe to say that the rubber shoe has done more to conserve the health of the human family than any other single article of apparel. In the manufacture of shoes the finest quality of rubber is received in wooden boxes 4 × 2 × 1½ feet, containing about 350 pounds in lumps of 1 to 75 pounds. These lumps are cut to suitable size, and are then ground and washed in the machine shown in Fig. 161, water and steam being sprayed on the rubber during the operation. It is then worked into sheets or mats between rolls. From the grinding room the sheets are taken to the mixing room, where lampblack, sulphur and other ingredients are added, and worked into it by being passed many times between heated rolls, the sheets being finally reduced to a thickness of less than 1/32 of an inch. The rubber sheets are then applied to a cloth backing by cloth calendering rolls, shown in Fig. 162, which are steam heated and by great pressure serve to incorporate the sheets of rubber and cloth into intimate and inseparable union. Out of this rubber fabric, which is made of different thicknesses for the upper, sole and heel, the patterns for the shoe are cut, and the parts are deftly fitted around the forms by girls, and secured by rubber cement, as shown in Fig. 163. The shoes are then covered with a coat of rubber varnish, and are put into cars and run into the vulcanizing ovens, where they remain from six to seven hours at a temperature of about 275°. The goods are then taken out, and after being inspected are boxed for the market. The vulcanizing is a very important part of the manufacture of a rubber shoe, for it is absolutely necessary in order to give them stability and wearing qualities. A shoe that had not been vulcanized would mash down, spread, become sticky and go to pieces after a few hours’ wear. The rubber shoe industry of the United States is carried on by about fifteen large companies, representing an investment of many millions of dollars, most of which companies are located in Massachusetts, Rhode Island and Connecticut. Some idea of the immensity of this industry may be obtained from the import statistics. In 1899 the United States alone imported crude rubber to the extent of 51,063,066 pounds, as much as 1,000,000 pounds a month coming from the single port of Para. The export of manufactured rubber goods for the same year amounted to $1,765,385. The statistics for Great Britain for 1896 showed the imports of rubber to that country to be one-third more than the imports of the United States. Germany also is a large consumer. The great Harburg-Vienna factories cover sixty-seven acres, are capitalized at 9,000,000 marks, and employ 3,500 hands. Much fine technical apparatus, toys, and balls are made here, the daily output of balls reaching 8,000. These, with the Noah’s arks of India rubber animals, are the delight of the little ones all over the world. Although so much in evidence about us, India rubber is not by any means a cheap material. Costing only five cents a pound when Goodyear commenced his experiments, it is now worth a dollar a pound, and is therefore much more expensive than any of the ordinary metals, woods, or building materials. Many substitutes in the form of compositions of various ingredients have been devised and patented, but no real substitute for nature’s product has yet been found. For many years old and worn out rubber goods were thrown away as worthless. Now all such rubber is reclaimed, and used in many grades of goods which do not require a pure gum. Insatiable as the demands of the trade may appear, there is no need to fear a rubber famine, for the forests of trees in South America and the East Indies are practically inexhaustible, and in the rich alluvial soil of their habitat nature’s processes of growth rapidly restore the decimation. [Illustration: FIG. 163.--MAKING RUBBER SHOES.] Since the time of Goodyear, the amplification of this art and the multiplication of uses for rubber, and its increased commercial importance, have gone on at such a rate of increase that to-day we may be said to be living in the rubber age. Its uses and applications are legion, and they extend literally from the cradle to the grave. When the baby comes into the world its introduction to India rubber begins at once with the nursing bottle and the gum cloth, and when the aged invalid takes leave of the world his last moments are soothed with the water bag and the rubber bed, and between these extremes we find it in evidence everywhere about us. In wearing apparel it extends from the crown of the head to the sole of the foot--rubber cap, coat, gloves, and shoes. The man has it in his suspenders and his pipe stem, the woman in her garters and dress shields, and the baby in its teething ring and rattle. The soldier stands on picket duty in the rain, and the rubber blanket protects him from rheumatism. If wounded, the surgeon dresses his mangled limb with rubber bandages, and when he gets well he has a rubber cushion on the end of his crutch, or on the foot of his artificial leg. If wounded in the mouth perhaps the government gives him a set of artificial teeth on a rubber plate. The rubber mat greets you at the front door, a little pad cushions the door stops and the backs of chairs, and a ring seals the mouth of the fruit jar. The whole array of toilet articles, including combs, brushes, mirrors, shoe horns, etc., are made from it. In the parlor it is found in picture frames and the piano cover; in the bath room the wash rag, water bag, rubber cup, and hose pipe of the shower bath are all made of it; in the play room are found rubber balls and toys of all kinds; in the kitchen the clothes wringer and the table cloth; in the dining room the handles of knives, and the tea tray, and what is more useful and more ubiquitous in the office than the rubber band, the rubber ruler, the pencil eraser, or the fountain pen? But these are only a few of the personal and indoor uses and applications. Rubber belting for machinery, fire engine and garden hose, steam engine packing, car springs, covers for carriages and the big guns of the navy, life preservers, billiard table cushions, and chemical and surgical apparatus in endless variety. The electrical world is almost entirely dependent upon it for the insulation of our ocean cables and electric light wires, for battery cups, and the insulating mountings of all electrical apparatus. The pneumatic bicycle tire could not exist without rubber, and the modern application of it to this use alone amounts to nearly four million pounds annually. Every automobile carriage takes twenty-five pounds of rubber for each tire, or 100 pounds altogether. This great and growing industry, together with the now common use of rubber tires on horse-drawn vehicles, raises the sum total of rubber employed in the arts to an enormous figure. That the sap of an uncultivated tree in a swampy, tropical, and malarial forest, thousands of miles from civilization, should cut so great a figure in the necessities of modern life, seems strange and unaccountable on any basis of probabilities. It is only another illustration of the possibilities of the patient and persistent work of the inventor. Charles Goodyear took this nearly worthless material, and made of it, as Parton said in 1865--“not a new material merely, but a new class of materials, applicable to a thousand divers uses. It was still India rubber, but its surface would not adhere, nor would it harden at any degree of cold, nor soften at any degree of heat. It was a cloth impervious to water; it was a paper that would not tear; it was a parchment that would not crease; it was leather which neither rain nor sun would injure; it was ebony that could be run into a mould; it was ivory that could be worked like wax; it was wood that never cracked, shrunk nor decayed. It was metal, ‘elastic metal,’ as Daniel Webster termed it, that could be wound round the finger, or tied into a knot, and which preserved its elasticity like steel. Trifling variations in the ingredients, in the proportion and in the heating, made it either pliable as kid, tougher than ox hide, as elastic as whalebone, or as rigid as flint.”