Edison: His Life and Inventions by Frank Lewis Dyer and Thomas Commerford Martin
1. As to the additional reference letters, I is a condenser J the source
6523 words | Chapter 51
of light, and K a reflector.
The positive film is moved intermittently but swiftly throughout its
length between the objective lens and a beam of light coming through the
condenser, being exposed by the shutter during the periods of rest. This
results in a projection of the photographs upon a screen in such rapid
succession as to present an apparently continuous photograph of the
successive positions of the moving objects, which, therefore, appear to
the human eye to be in motion.
The first claim of Reissue Patent No. 12,192 describes the film. It
reads as follows:
"An unbroken transparent or translucent tape-like photographic film
having thereon uniform, sharply defined, equidistant photographs of
successive positions of an object in motion as observed from a single
point of view at rapidly recurring intervals of time, such photographs
being arranged in a continuous straight-line sequence, unlimited in
number save by the length of the film, and sufficient in number to
represent the movements of the object throughout an extended period of
time."
XVI. EDISON'S ORE-MILLING INVENTIONS
THE wide range of Edison's activities in this department of the arts is
well represented in the diversity of the numerous patents that have been
issued to him from time to time. These patents are between fifty and
sixty in number, and include magnetic ore separators of ten distinct
types; also breaking, crushing, and grinding rolls, conveyors,
dust-proof bearings, screens, driers, mixers, bricking apparatus and
machines, ovens, and processes of various kinds.
A description of the many devices in each of these divisions would
require more space than is available; hence, we shall confine ourselves
to a few items of predominating importance, already referred to in the
narrative, commencing with the fundamental magnetic ore separator, which
was covered by United States Patent No. 228,329, issued June 1, 1880.
The illustration here presented is copied from the drawing forming part
of this patent. A hopper with adjustable feed is supported several feet
above a bin having a central partition. Almost midway between the hopper
and the bin is placed an electromagnet whose polar extension is so
arranged as to be a little to one side of a stream of material falling
from the hopper. Normally, a stream of finely divided ore falling from
the hopper would fall into that portion of the bin lying to the left
of the partition. If, however, the magnet is energized from a source of
current, the magnetic particles in the falling stream are attracted
by and move toward the magnet, which is so placed with relation to
the falling material that the magnetic particles cannot be attracted
entirely to the magnet before gravity has carried them past. Hence,
their trajectory is altered, and they fall on the right-hand side of
the partition in the bin, while the non-magnetic portion of the stream
continues in a straight line and falls on the other side, thus effecting
a complete separation.
This simple but effective principle was the one employed by Edison
in his great concentrating plant already described. In practice, the
numerous hoppers, magnets, and bins were many feet in length; and they
were arranged in batteries of varied magnetic strength, in order
that the intermingled mass of crushed rock and iron ore might be
more thoroughly separated by being passed through magnetic fields of
successively increasing degrees of attracting power. Altogether there
were about four hundred and eighty of these immense magnets in the
plant, distributed in various buildings in batteries as above mentioned,
the crushed rock containing the iron ore being delivered to them by
conveyors, and the gangue and ore being taken away after separation by
two other conveyors and delivered elsewhere. The magnetic separators at
first used by Edison at this plant were of the same generality as the
ones employed some years previously in the separation of sea-shore sand,
but greatly enlarged and improved. The varied experiences gained in
the concentration of vast quantities of ore led naturally to a greater
development, and several new types and arrangements of magnetic
separators were evolved and elaborated by him from first to last, during
the progress of the work at the concentrating plant.
The magnetic separation of iron from its ore being the foundation idea
of the inventions now under discussion, a consideration of the separator
has naturally taken precedence over those of collateral but inseparable
interest. The ore-bearing rock, however, must first be ground to powder
before it can be separated; hence, we will now begin at the root of
this operation and consider the "giant rolls," which Edison devised
for breaking huge masses of rock. In his application for United States
Patent No. 672,616, issued April 23, 1901, applied for on July 16, 1897,
he says: "The object of my invention is to produce a method for the
breaking of rock which will be simple and effective, will not require
the hand-sledging or blasting of the rock down to pieces of moderate
size, and will involve the consumption of a small amount of power."
While this quotation refers to the method as "simple," the patent under
consideration covers one of the most bold and daring projects that
Edison has ever evolved. He proposed to eliminate the slow and expensive
method of breaking large boulders manually, and to substitute therefor
momentum and kinetic energy applied through the medium of massive
machinery, which, in a few seconds, would break into small pieces a rock
as big as an ordinary upright cottage piano, and weighing as much as six
tons. Engineers to whom Edison communicated his ideas were unanimous
in declaring the thing an impossibility; it was like driving two
express-trains into each other at full speed to crack a great rock
placed between them; that no practical machinery could be built to
stand the terrific impact and strains. Edison's convictions were
strong, however, and he persisted. The experiments were of heroic size,
physically and financially, but after a struggle of several years and
an expenditure of about $100,000, he realized the correctness and
practicability of his plans in the success of the giant rolls, which
were the outcome of his labors.
The giant rolls consist of a pair of iron cylinders of massive size and
weight, with removable wearing plates having irregular surfaces formed
by projecting knobs. These rolls are mounted side by side in a very
heavy frame (leaving a gap of about fourteen inches between them), and
are so belted up with the source of power that they run in opposite
directions. The giant rolls described by Edison in the above-named
patent as having been built and operated by him had a combined weight of
167,000 pounds, including all moving parts, which of themselves weighed
about seventy tons, each roll being six feet in diameter and five feet
long. A top view of the rolls is shown in the sketch, one roll and one
of its bearings being shown in section.
In Fig. 2 the rolls are illustrated diagrammatically. As a sketch of
this nature, even if given with a definite scale, does not always carry
an adequate idea of relative dimensions to a non-technical reader,
we present in Fig. 3 a perspective illustration of the giant rolls as
installed in the concentrating plant.
In practice, a small amount of power is applied to run the giant rolls
gradually up to a surface speed of several thousand feet a minute. When
this high speed is attained, masses of rock weighing several tons in one
or more pieces are dumped into a hopper which guides them into the gap
between the rapidly revolving rolls. The effect is to partially arrest
the swift motion of the rolls instantaneously, and thereby develop and
expend an enormous amount of kinetic energy, which with pile-driver
effect cracks the rocks and breaks them into pieces small enough to
pass through the fourteen-inch gap. As the power is applied to the rolls
through slipping friction-clutches, the speed of the driving-pulleys is
not materially reduced; hence the rolls may again be quickly speeded up
to their highest velocity while another load of rock is being hoisted
in position to be dumped into the hopper. It will be obvious from the
foregoing that if it were attempted to supply the great energy necessary
for this operation by direct application of steam-power, an engine of
enormous horse-power would be required, and even then it is doubtful
if one could be constructed of sufficient strength to withstand the
terrific strains that would ensue. But the work is done by the great
momentum and kinetic energy obtained by speeding up these tremendous
masses of metal, and then suddenly opposing their progress, the
engine being relieved of all strain through the medium of the slipping
friction-clutches. Thus, this cyclopean operation may be continuously
conducted with an amount of power prodigiously inferior, in proportion,
to the results accomplished.
The sketch (Fig. 4) showing a large boulder being dumped into the
hopper, or roll-pit, will serve to illustrate the method of feeding
these great masses of rock to the rolls, and will also enable the reader
to form an idea of the rapidity of the breaking operation, when it is
stated that a boulder of the size represented would be reduced by
the giant rolls to pieces a trifle larger than a man's head in a few
seconds.
After leaving the giant rolls the broken rock passed on through other
crushing-rolls of somewhat similar construction. These also were
invented by Edison, but antedated those previously described; being
covered by Patent No. 567,187, issued September 8, 1896. These rolls
were intended for the reducing of "one-man-size" rocks to small pieces,
which at the time of their original inception was about the standard
size of similar machines. At the Edison concentrating plant the broken
rock, after passing through these rolls, was further reduced in size by
other rolls, and was then ready to be crushed to a fine powder through
the medium of another remarkable machine devised by Edison to meet his
ever-recurring and well-defined ideas of the utmost economy and
efficiency.
NOTE.--Figs. 3 and 4 are reproduced from similar sketches on pages 84
and 85 of McClure's Magazine for November, 1897, by permission of S. S.
McClure Co.
The best fine grinding-machines that it was then possible to obtain were
so inefficient as to involve a loss of 82 per cent. of the power
applied. The thought of such an enormous loss was unbearable, and he did
not rest until he had invented and put into use an entirely new
grinding-machine, which was called the "three-high" rolls. The device
was covered by a patent issued to him on November 21, 1899, No. 637,327.
It was a most noteworthy invention, for it brought into the art not only
a greater efficiency of grinding than had ever been dreamed of before,
but also a tremendous economy by the saving of power; for whereas the
previous efficiency had been 18 per cent. and the loss 82 per cent.,
Edison reversed these figures, and in his three-high rolls produced a
working efficiency of 84 per cent., thus reducing the loss of power by
friction to 16 per cent. A diagrammatic sketch of this remarkable
machine is shown in Fig. 5, which shows a front elevation with the
casings, hopper, etc., removed, and also shows above the rolls the rope
and pulleys, the supports for which are also removed for the sake of
clearness in the illustration.
For the convenience of the reader, in referring to Fig. 5, we will
repeat the description of the three-high rolls, which is given on pages
487 and 488 of the preceding narrative.
In the two end-pieces of a heavy iron frame were set three rolls, or
cylinders--one in the centre, another below, and the other above--all
three being in a vertical line. These rolls were about three feet in
diameter, made of cast-iron, and had face-plates of chilled-iron. [31]
The lowest roll was set in a fixed bearing at the bottom of the frame,
and, therefore, could only turn around on its axis. The middle and top
rolls were free to move up or down from and toward the lower roll, and
the shafts of the middle and upper rolls were set in a loose bearing
which could slip up and down in the iron frame. It will be apparent,
therefore, that any material which passed in between the top and the
middle rolls, and the middle and bottom rolls, could be ground as fine
as might be desired, depending entirely upon the amount of pressure
applied to the loose rolls. In operation the material passed first
through the upper and middle rolls, and then between the middle and
lowest rolls.
[Footnote 31: The faces of these rolls were smooth, but as
three-high rolls came into use later in Edison's Portland
cement operations the faces were corrugated so as to fit
into each other, gear-fashion, to provide for a high rate of
feed]
This pressure was applied in a most ingenious manner. On the ends of the
shafts of the bottom and top rolls there were cylindrical sleeves, or
bearings, having seven sheaves in which was run a half-inch endless wire
rope. This rope was wound seven times over the sheaves as above, and led
upward and over a single-groove sheave, which was operated by the piston
of an air-cylinder, and in this manner the pressure was applied to the
rolls. It will be seen, therefore that the system consisted in a single
rope passed over sheaves and so arranged that it could be varied
in length, thus providing for elasticity in exerting pressure and
regulating it as desired. The efficiency of this system was incomparably
greater than that of any other known crusher or grinder, for while a
pressure of one hundred and twenty-five thousand pounds could be exerted
by these rolls, friction was almost entirely eliminated, because the
upper and lower roll bearings turned with the rolls and revolved in the
wire rope, which constituted the bearing proper.
Several other important patents have been issued to Edison for crushing
and grinding rolls, some of them being for elaborations and improvements
of those above described but all covering methods of greater economy and
effectiveness in rock-grinding.
Edison's work on conveyors during the period of his ore-concentrating
labors was distinctively original, ingenious and far in advance of
the times. His conception of the concentrating problem was broad and
embraced an entire system, of which a principal item was the continuous
transfer of enormous quantities of material from place to place at
the lowest possible cost. As he contemplated the concentration of six
thousand tons daily, the expense of manual labor to move such an immense
quantity of rock, sand, and ore would be absolutely prohibitive. Hence,
it became necessary to invent a system of conveyors that would be
capable of transferring this mass of material from one place to another.
And not only must these conveyors be capable of carrying the material,
but they must also be devised so that they would automatically receive
and discharge their respective loads at appointed places. Edison's
ingenuity, engineering ability, and inventive skill were equal to the
task, however, and were displayed in a system and variety of conveyors
that in practice seemed to act with almost human discrimination. When
fully installed throughout the plant, they automatically transferred
daily a mass of material equal to about one hundred thousand cubic feet,
from mill to mill, covering about a mile in the transit. Up and down,
winding in and out, turning corners, delivering material from one to
another, making a number of loops in the drying-oven, filling up bins
and passing on to the next when they were full, these conveyors in
automatic action seemingly played their part with human intelligence,
which was in reality the reflection of the intelligence and ingenuity
that had originally devised them and set them in motion.
Six of Edison's patents on conveyors include a variety of devices that
have since came into broad general use for similar work, and have been
the means of effecting great economies in numerous industries of widely
varying kinds. Interesting as they are, however, we shall not attempt to
describe them in detail, as the space required would be too great. They
are specified in the list of patents following this Appendix, and may be
examined in detail by any interested student.
In the same list will also be found a large number of Edison's patents
on apparatus and methods of screening, drying, mixing, and briquetting,
as well as for dust-proof bearings, and various types and groupings
of separators, all of which were called forth by the exigencies and
magnitude of his great undertaking, and without which he could not
possibly have attained the successful physical results that crowned his
labors. Edison's persistence in reducing the cost of his operations is
noteworthy in connection with his screening and drying inventions, in
which the utmost advantage is taken of the law of gravitation. With
its assistance, which cost nothing, these operations were performed
perfectly. It was only necessary to deliver the material at the top of
the chambers, and during its natural descent it was screened or dried as
the case might be.
All these inventions and devices, as well as those described in detail
above (except magnetic separators and mixing and briquetting machines),
are being used by him to-day in the manufacture of Portland cement, as
that industry presents many of the identical problems which presented
themselves in relation to the concentration of iron ore.
XVII. THE LONG CEMENT KILN
IN this remarkable invention, which has brought about a striking
innovation in a long-established business, we see another characteristic
instance of Edison's incisive reasoning and boldness of conception
carried into practical effect in face of universal opinions to the
contrary.
For the information of those unacquainted with the process of
manufacturing Portland cement, it may be stated that the material
consists preliminarily of an intimate mixture of cement rock and
limestone, ground to a very fine powder. This powder is technically
known in the trade as "chalk," and is fed into rotary kilns and
"burned"; that is to say, it is subjected to a high degree of heat
obtained by the combustion of pulverized coal, which is injected
into the interior of the kiln. This combustion effects a chemical
decomposition of the chalk, and causes it to assume a plastic
consistency and to collect together in the form of small spherical
balls, which are known as "clinker." Kilns are usually arranged with
a slight incline, at the upper end of which the chalk is fed in and
gradually works its way down to the interior flame of burning fuel at
the other end. When it arrives at the lower end, the material has been
"burned," and the clinker drops out into a receiving chamber below. The
operation is continuous, a constant supply of chalk passing in at one
end of the kiln and a continuous dribble of clinker-balls dropping
out at the other. After cooling, the clinker is ground into very fine
powder, which is the Portland cement of commerce.
It is self-evident that an ideal kiln would be one that produced the
maximum quantity of thoroughly clinkered material with a minimum amount
of fuel, labor, and investment. When Edison was preparing to go into
the cement business, he looked the ground over thoroughly, and, after
considerable investigation and experiment, came to the conclusion that
prevailing conditions as to kilns were far from ideal.
The standard kilns then in use were about sixty feet in length, with an
internal diameter of about five feet. In all rotary kilns for burning
cement, the true clinkering operation takes place only within a limited
portion of their total length, where the heat is greatest; hence the
interior of the kiln may be considered as being divided longitudinally
into two parts or zones--namely, the combustion, or clinkering, zone,
and the zone of oncoming raw material. In the sixty-foot kiln the length
of the combustion zone was about ten feet, extending from a point six or
eight feet from the lower, or discharge, end to a point about eighteen
feet from that end. Consequently, beyond that point there was a zone of
only about forty feet, through which the heated gases passed and came
in contact with the oncoming material, which was in movement down toward
the clinkering zone. Since the bulk of oncoming material was small,
the gases were not called upon to part with much of their heat, and
therefore passed on up the stack at very high temperatures, ranging from
1500 degrees to 1800 degrees Fahr. Obviously, this heat was entirely
lost.
An additional loss of efficiency arose from the fact that the material
moved so rapidly toward the combustion zone that it had not given up
all its carbon dioxide on reaching there; and by the giving off of
large quantities of that gas within the combustion zone, perfect and
economical combustion of coal could not be effected.
The comparatively short length of the sixty-foot kiln not only limited
the amount of material that could be fed into it, but the limitation in
length of the combustion zone militated against a thorough clinkering of
the material, this operation being one in which the elements of time and
proper heat are prime considerations. Thus the quantity of good clinker
obtainable was unfavorably affected. By reason of these and other
limitations and losses, it had been possible, in practice, to obtain
only about two hundred and fifty barrels of clinker per day of
twenty-four hours; and that with an expenditure for coal proportionately
equal to about 29 to 33 per cent. of the quantity of clinker produced,
even assuming that all the clinker was of good quality.
Edison realized that the secret of greater commercial efficiency and
improvement of quality lay in the ability to handle larger quantities
of material within a given time, and to produce a more perfect product
without increasing cost or investment in proportion. His reasoning led
him to the conclusion that this result could only be obtained through
the use of a kiln of comparatively great length, and his investigations
and experiments enabled him to decide upon a length of one hundred and
fifty feet, but with an increase in diameter of only six inches to a
foot over that of the sixty-foot kiln.
The principal considerations that influenced Edison in making this
radical innovation may be briefly stated as follows:
First. The ability to maintain in the kiln a load from five to seven
times greater than ordinarily employed, thereby tending to a more
economical output.
Second. The combustion of a vastly increased bulk of pulverized coal
and a greatly enlarged combustion zone, extending about forty feet
longitudinally into the kiln--thus providing an area within which
the material might be maintained in a clinkering temperature for a
sufficiently long period to insure its being thoroughly clinkered from
periphery to centre.
Third. By reason of such a greatly extended length of the zone of
oncoming material (and consequently much greater bulk), the gases and
other products of combustion would be cooled sufficiently between the
combustion zone and the stack so as to leave the kiln at a comparatively
low temperature. Besides, the oncoming material would thus be gradually
raised in temperature instead of being heated abruptly, as in the
shorter kilns.
Fourth. The material having thus been greatly raised in temperature
before reaching the combustion zone would have parted with substantially
all its carbon dioxide, and therefore would not introduce into the
combustion zone sufficient of that gas to disturb the perfect character
of the combustion.
Fifth. On account of the great weight of the heavy load in a long kiln,
there would result the formation of a continuous plastic coating on that
portion of the inner surface of the kiln where temperatures are
highest. This would effectively protect the fire-brick lining from the
destructive effects of the heat.
Such, in brief, were the essential principles upon which Edison based
his conception and invention of the long kiln, which has since become so
well known in the cement business.
Many other considerations of a minor and mechanical nature, but which
were important factors in his solution of this difficult problem, are
worthy of study by those intimately associated with or interested in the
art. Not the least of the mechanical questions was settled by Edison's
decision to make this tremendously long kiln in sections of cast-iron,
with flanges, bolted together, and supported on rollers rotated by
electric motors. Longitudinal expansion and thrust were also important
factors to be provided for, as well as special devices to prevent the
packing of the mass of material as it passed in and out of the kiln.
Special provision was also made for injecting streams of pulverized coal
in such manner as to create the largely extended zone of combustion. As
to the details of these and many other ingenious devices, we must refer
the curious reader to the patents, as it is merely intended in these
pages to indicate in a brief manner the main principles of Edison's
notable inventions. The principal United States patent on the long kiln
was issued October 24, 1905, No. 802,631.
That his reasonings and deductions were correct in this case have been
indubitably proven by some years of experience with the long kiln in its
ability to produce from eight hundred to one thousand barrels of
good clinker every twenty-four hours, with an expenditure for coal
proportionately equal to about only 20 per cent. of the quantity of
clinker produced.
To illustrate the long cement kiln by diagram would convey but little
to the lay mind, and we therefore present an illustration (Fig. 1) of
actual kilns in perspective, from which sense of their proportions may
be gathered.
XVIII. EDISON'S NEW STORAGE BATTERY
GENERICALLY considered, a "battery" is a device which generates electric
current. There are two distinct species of battery, one being known as
"primary," and the other as "storage," although the latter is sometimes
referred to as a "secondary battery" or "accumulator." Every type of
each of these two species is essentially alike in its general make-up;
that is to say, every cell of battery of any kind contains at least
two elements of different nature immersed in a more or less liquid
electrolyte of chemical character. On closing the circuit of a primary
battery an electric current is generated by reason of the chemical
action which is set up between the electrolyte and the elements.
This involves a gradual consumption of one of the elements and a
corresponding exhaustion of the active properties of the electrolyte. By
reason of this, both the element and the electrolyte that have been used
up must be renewed from time to time, in order to obtain a continued
supply of electric current.
The storage battery also generates electric current through chemical
action, but without involving the constant repriming with active
materials to replace those consumed and exhausted as above mentioned.
The term "storage," as applied to this species of battery, is,
however, a misnomer, and has been the cause of much misunderstanding
to nontechnical persons. To the lay mind a "storage" battery presents
itself in the aspect of a device in which electric energy is STORED,
just as compressed air is stored or accumulated in a tank. This view,
however, is not in accordance with facts. It is exactly like the primary
battery in the fundamental circumstance that its ability for generating
electric current depends upon chemical action. In strict terminology it
is a "reversible" battery, as will be quite obvious if we glance briefly
at its philosophy. When a storage battery is "charged," by having an
electric current passed through it, the electric energy produces a
chemical effect, adding oxygen to the positive plate, and taking oxygen
away from the negative plate. Thus, the positive plate becomes oxidized,
and the negative plate reduced. After the charging operation is
concluded the battery is ready for use, and upon its circuit being
closed through a translating device, such as a lamp or motor, a
reversion ("discharge") takes place, the positive plate giving up its
oxygen, and the negative plate being oxidized. These chemical actions
result in the generation of an electric current as in a primary battery.
As a matter of fact, the chemical actions and reactions in a storage
battery are much more complex, but the above will serve to afford the
lay reader a rather simple idea of the general result arrived at through
the chemical activity referred to.
The storage battery, as a commercial article, was introduced into the
market in the year 1881. At that time, and all through the succeeding
years, until about 1905, there was only one type that was recognized as
commercially practicable--namely, that known as the lead-sulphuric-acid
cell, consisting of lead plates immersed in an electrolyte of dilute
sulphuric acid. In the year last named Edison first brought out his new
form of nickel-iron cell with alkaline electrolyte, as we have related
in the preceding narrative. Early in the eighties, at Menlo Park, he had
given much thought to the lead type of storage battery, and during the
course of three years had made a prodigious number of experiments in the
direction of improving it, probably performing more experiments in that
time than the aggregate of those of all other investigators. Even
in those early days he arrived at the conclusion that the
lead-sulphuric-acid combination was intrinsically wrong, and did not
embrace the elements of a permanent commercial device. He did not at
that time, however, engage in a serious search for another form of
storage battery, being tremendously occupied with his lighting system
and other matters.
It may here be noted, for the information of the lay reader, that the
lead-acid type of storage battery consists of two or more lead plates
immersed in dilute sulphuric acid and contained in a receptacle of
glass, hard rubber, or other special material not acted upon by acid.
The plates are prepared and "formed" in various ways, and the chemical
actions are similar to those above stated, the positive plate being
oxidized and the negative reduced during "charge," and reversed during
"discharge." This type of cell, however, has many serious disadvantages
inherent to its very nature. We will name a few of them briefly.
Constant dropping of fine particles of active material often causes
short-circuiting of the plates, and always necessitates occasional
washing out of cells; deterioration through "sulphation" if discharge
is continued too far or if recharging is not commenced quickly enough;
destruction of adjacent metalwork by the corrosive fumes given out
during charge and discharge; the tendency of lead plates to "buckle"
under certain conditions; the limitation to the use of glass, hard
rubber, or similar containers on account of the action of the acid; and
the immense weight for electrical capacity. The tremendously complex
nature of the chemical reactions which take place in the lead-acid
storage battery also renders it an easy prey to many troublesome
diseases.
In the year 1900, when Edison undertook to invent a storage battery, he
declared it should be a new type into which neither sulphuric nor
any other acid should enter. He said that the intimate and continued
companionship of an acid and a metal was unnatural, and incompatible
with the idea of durability and simplicity. He furthermore stated that
lead was an unmechanical metal for a battery, being heavy and lacking
stability and elasticity, and that as most metals were unaffected by
alkaline solutions, he was going to experiment in that direction. The
soundness of his reasoning is amply justified by the perfection of
results obtained in the new type of storage battery bearing his name,
and now to be described.
The essential technical details of this battery are fully described
in an article written by one of Edison's laboratory staff, Walter
E. Holland, who for many years has been closely identified with the
inventor's work on this cell The article was published in the Electrical
World, New York, April 28, 1910; and the following extracts therefrom
will afford an intelligent comprehension of this invention:
"The 'A' type Edison cell is the outcome of nine years of costly
experimentation and persistent toil on the part of its inventor and his
associates....
"The Edison invention involves the use of an entirely new
voltaic combination in an alkaline electrolyte, in place of the
lead-lead-peroxide combination and acid electrolyte, characteristic of
all other commercial storage batteries. Experience has proven that
this not only secures durability and greater output per unit-weight of
battery, but in addition there is eliminated a long list of troubles and
diseases inherent in the lead-acid combination....
"The principle on which the action of this new battery is based is
the oxidation and reduction of metals in an electrolyte which does not
combine with, and will not dissolve, either the metals or their oxides;
and an electrolyte, furthermore, which, although decomposed by the
action of the battery, is immediately re-formed in equal quantity; and
therefore in effect is a CONSTANT element, not changing in density or in
conductivity.
"A battery embodying this basic principle will have features of great
value where lightness and durability are desiderata. For instance, the
electrolyte, being a constant factor, as explained, is not required in
any fixed and large amount, as is the case with sulphuric acid in the
lead battery; thus the cell may be designed with minimum distancing of
plates and with the greatest economy of space that is consistent with
safe insulation and good mechanical design. Again, the active materials
of the electrodes being insoluble in, and absolutely unaffected by, the
electrolyte, are not liable to any sort of chemical deterioration by
action of the electrolyte--no matter how long continued....
"The electrolyte of the Edison battery is a 21 per cent. solution of
potassium hydrate having, in addition, a small amount of lithium
hydrate. The active metals of the electrodes--which will oxidize and
reduce in this electrolyte without dissolution or chemical
deterioration--are nickel and iron. These active elements are not put in
the plates AS METALS; but one, nickel, in the form of a hydrate, and the
other, iron, as an oxide.
"The containing cases of both kinds of active material (Fig. 1), and
their supporting grids (Fig. 2), as well as the bolts, washers, and nuts
used in assembling (Fig. 3), and even the retaining can and its cover
(Fig. 4), are all made of nickel-plated steel--a material in which
lightness, durability and mechanical strength are most happily
combined, and a material beyond suspicion as to corrosion in an alkaline
electrolyte....
"An essential part of Edison's discovery of active masetials for
an alkaline storage battery was the PREPARATION of these materials.
Metallic powder of iron and nickel, or even oxides of these metals,
prepared in the ordinary way, are not chemically active in a sufficient
degree to work in a battery. It is only when specially prepared iron
oxide of exceeding fineness, and nickel hydrate conforming to certain
physical, as well as chemical, standards can be made that the alkaline
battery is practicable. Needless to say, the working out of the
conditions and processes of manufacture of the materials has involved
great ingenuity and endless experimentation."
The article then treats of Edison's investigations into means for
supporting and making electrical connection with the active materials,
showing some of the difficulties encountered and the various discoveries
made in developing the perfected cell, after which the writer continues
his description of the "A" type cell, as follows:
"It will be seen at once that the construction of the two kinds of plate
is radically different. The negative or iron plate (Fig. 5) has the
familiar flat-pocket construction. Each negative contains twenty-four
pockets--a pocket being 1/2 inch wide by 3 inches long, and having a
maximum thickness of a little more than 1/8 inch. The positive or nickel
plate (Fig. 6) is seen to consist of two rows of round rods or pencils,
thirty in number, held in a vertical position by a steel support-frame.
The pencils have flat flanges at the ends (formed by closing in the
metal case), by which they are supported and electrical connection is
made. The frame is slit at the inner horizontal edges, and then folded
in such a way as to make individual clamping-jaws for each end-flange.
The clamping-in is done at great pressure, and the resultant plate has
great rigidity and strength.
"The perforated tubes into which the nickel active material is loaded
are made of nickel-plated steel of high quality. They are put together
with a double-lapped spiral seam to give expansion-resisting qualities,
and as an additional precaution small metal rings are slipped on the
outside. Each tube is 1/4 inch in diameter by 4 1/8 inches long, add has
eight of the reinforcing rings.
"It will be seen that the 'A' positive plate has been given the
theoretically best design to prevent expansion and overcome trouble from
that cause. Actual tests, long continued under very severe conditions,
have shown that the construction is right, and fulfils the most sanguine
expectations."
Mr. Holland in his article then goes on to explain the development of
the nickel flakes as the conducting factor in the positive element, but
as this has already been described in Chapter XXII, we shall pass on to
a later point, where he says:
"An idea of the conditions inside a loaded tube can best be had by
microscopic examination. Fig. 7 shows a magnified section of a regularly
loaded tube which has been sawed lengthwise. The vertical bounding walls
are edges of the perforated metal containing tube; the dark horizontal
lines are layers of nickel flake, while the light-colored thicker layers
represent the nickel hydrate. It should be noted that the layers of
flake nickel extend practically unbroken across the tube and make
contact with the metal wall at both sides. These metal layers conduct
current to or from the active nickel hydrate in all parts of the tube
very efficiently. There are about three hundred and fifty layers of
each kind of material in a 4 1/8-inch tube, each layer of nickel hydrate
being about 0.01 inch thick; so it will be seen that the current does
not have to penetrate very far into the nickel hydrate--one-half a
layer's thickness being the maximum distance. The perforations of
the containing tube, through which the electrolyte reaches the active
material, are also shown in Fig. 7."
In conclusion, the article enumerates the chief characteristics of the
Edison storage battery which fit it preeminently for transportation
service, as follows: 1. No loss of active material, hence no
sediment short-circuits. 2. No jar breakage. 3. Possibility of quick
disconnection or replacement of any cell without employment of skilled
labor. 4. Impossibility of "buckling" and harmlessness of a dead
short-circuit. 5. Simplicity of care required. 6. Durability of
materials and construction. 7. Impossibility of "sulphation." 8. Entire
absence of corrosive fumes. 9. Commercial advantages of light weight.
Reading Tips
Use arrow keys to navigate
Press 'N' for next chapter
Press 'P' for previous chapter